Journal of the Chemical Society. Perkin transactions II p. 953 - 957 (1981)
Update date:2022-07-29
Topics:
Rees, John C.
Whittaker, David
The reactions of the isomeric thujan-3-ols with fluorosulphuric acid to give 2,3-dimethyl-4-isopropylcyclopentenium ion have been investigated.The initial ring opening involves at least two mechanisms yielding a carbocation and an olefin.Subsequent reaction, possibly by elimination and olefin shift, gives the 2,3-dimethyl-4-isopropylcyclopent-2-enol, which rapidly ionises to the observed ion.The reaction has been studied by means of deuterium tracers, in the solvent and in the substrate, and by comparison of the reaction with those of related substrates.
View MoreXinchang Yueding Chemical Co., Ltd.
Contact:86-571-56926323
Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
Jiangsu Wanlong Chemical Co., Ltd.
website:http://www.wanlongchem.com
Contact:+86-511-86810993 0086-511-8681 0888;
Address:Quanzhou Town, Danyang City, Jiangsu
Contact:+86-570-4336358
Address:No.87 Building,Tianqian,Sidu Town
Zhangjiagang Jianing Import & Export Co.,Ltd.
Contact:086-512-55379012 13913607595
Address:NO.1 Guotai North Road Zhangjiagang Economic Development Zone,215600,Jiangsu,China
Anyang Double Circle Auxiliary CO.,LTD
Contact:0086-134 6082 4403
Address:dongfeng road, anyang city, henan province,china
Doi:10.1016/j.bmc.2017.08.019
(2018)Doi:10.1016/j.bmcl.2004.03.074
(2004)Doi:10.1021/ja00794a043
(1973)Doi:10.1021/ja00804a045
(1973)Doi:10.1021/jo00004a044
(1991)Doi:10.1248/cpb.21.1388
(1973)
