Tetrahedron p. 2619 - 2624 (1988)
Update date:2022-08-04
Topics:
Downie, Ian M.
Heaney, Harry
Kemp, Graham
A method, which involves no molecular rearrangement, and which is also stereospecific, for the preparation of alkyl-aryl ethers and thioethers is described.Stable alkoxyphosphonium salts, R-O-P(1+)(NMe2)3 PF6(1-), have been prepared and treated with phenols and thiophenols, under basic conditions, to yield the corresponding alkyl-aryl ethers and thioethers respectively.
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