Tetrahedron Letters p. 4643 - 4647 (1999)
Update date:2022-08-02
Topics:
Chemler, Sherry R.
Roush, William R.
Allylation and crotylation reactions of 2,3-anti-β-hydroxy-α-methyl aldehydes 10 and 11 with allyl and crotyltrifluorosilanes 2, 8 and 9 proceed with high selectivity via the bicyclic chelated transition states 3 and 30. In contrast, analogous allylation
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