Journal of Fluorine Chemistry p. 83 - 88 (1995)
Update date:2022-08-05
Topics:
Russo, A.
Montanari, V.
Navarrini, W.
DesMarteau, Darryl D.
The reaction of fluoroxydifluoromethyl trifluoromethyl peroxide, CF3OOCF2OF (1), with fluoroolefins leads to the formation of novel fluorinated peroxides as major products.When 1 was added to 1,2-dichloro-1,2-difluoroethylene, CFCl=CFCl, under controlled conditions, the formation of 4,5-dichloro-2,2,4,5-tetrafluoro-1,3-dioxolane was also observed.A mechanism is proposed to rationalize these results. - Keywords: Fluoroolefins; Fluoroxydifluoromethyl trifluoromethyl peroxide; Synthesis; IR spectroscopy; NMR spectroscopy; Mass spectrometry
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