Tetrahedron Letters p. 637 - 640 (1989)
Update date:2022-08-04
Topics:
Matlin, Albert R.
Jin, Kyo
Irradiation of 2,7-cyclooctadienone 1 produces cis,trans-2,7-cyclooctadienone 5 which has been characterized by low temperature 13C NMR.Dienone 5 is in equilibrium with a zwitterionic oxyallyl species 6 via B, B' bond formation.Zwitterion 6 forms cycloadducts with ethyl vinyl ether and 2-methoxypropene.
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