Direct Observation of Metastable Intermediates in the Photochemical Ring Closure of 2-Naphthyl Vinyl Sulfides

DOI: 10.1021/ja00331a026

Source and publish data:

Journal of the American Chemical Society p. 5553 - 5559 (1984)

Update date:2022-09-26

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Authors:

Herkstroeter, William G.

Schultz, Arthur G.

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Article abstract of DOI:10.1021/ja00331a026

The mechanism for the photochemical cyclization of 2-naphthyl vinyl sulfides was the subject of flash photolysis investigations.Five such sulfides with structural variations each formed phototransient species with absorption maxima near 650 nm.Kinetic ana

Full text of DOI:10.1021/ja00331a026

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