
Journal of Organometallic Chemistry p. 105 - 110 (1980)
Update date:2022-08-03
Topics:
Paoli, Marco-A. De
Oliveira, Sonia M. De
Galembeck, Fernando
A matrix technique for the study of photochemical preparation of unstable and air-sensitive organometallic compounds is described.The matrix used is a film of inert polymer, such as polytetrafluorethylene (PTFE).The films containing the compounds can be handled under normal ambient conditions.The method is used to study the products and photochemical reactions of pentacarbonyliron with olefins.
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Doi:10.1021/jm970806i
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