Phytochemistry p. 1055 - 1059 (1997)
Update date:2022-08-04
Topics:
Hanson, James R.
Hitchcock, Peter B.
Jarvis, Andrew G.
The hydroxylation at C-17 in aphidicolin biosynthesis is inhibited by a 17-thiol. A metabolite hydroxylated at C-17 and retaining the cyclopropane ring was obtained from 3α,18-dihydroxy-15β,16β-methanoaphidicolane whilst aphidicolin itself was obtained from 3α,18-dihydroxyaphidicolane when these substrates were incubated with the fungus, Cephalosporium aphidicola.
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