Tetrahedron p. 781 - 784 (1985)
Update date:2022-08-05
Topics:
Andrews, Laura E.
Bonnett, Raymond
Appelman, Evan H.
The chemical reactions of hypofluorous acid with aromatic and olefinic substrates show considerable variety.Hypofluorous acid reacts with naphthalene to give 1-naphthol, 2-naphthol and 1,4-naphthoquinone: with benzothiophen to give the 1,1-dioxide; with trans-stilbene to give threo-2-fluoro-1-hydroxy-1,2-diphenylethane, benzophenone and diphenylacetaldehyde: and with cholesteryl acetate to give the two epoxides ( α:β=6.3:1 ) and two fluorohydrins ( 6β-fluoro-5-β-ol and 5α-fluoro-6β-ol ).
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