DIASTEREOSELECTION IN A DIRECTED CROSSED ALDOL REACTION BETWEEN TWO POLYOXYGENATED KETONES EMPLOYING TIN(II) ENOLATES. A FACILE STEREOSELECTIVE SYNTHESIS OF ETHYL 2-C-METHYL-DL-LYXOFURANOSIDE

DOI: 10.1246/cl.1983.595

Source and publish data:

Chemistry Letters p. 595 - 598 (1983)

Update date:2022-08-04

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Authors:

Stevens, Rodney W.

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1983.595

Tin(II) enolates of 1,3-dihydroxy-2-propanone derivatives react with a second ketone, methyl pyruvate, under mild conditions to afford the corresponding anti-crossed aldol products in moderate to excellent yields.Facile elaboration to the branched-chain s

Full text of DOI:10.1246/cl.1983.595

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