Organic Letters p. 5449 - 5451 (2016)
Update date:2022-08-04
Topics:
Li, Jiaming
Grubbs, Robert H.
Stoltz, Brian M.
A mild aerobic intramolecular aminoacetoxylation method for the synthesis of pyrrolidine and indoline derivatives was achieved using molecular oxygen as the oxidant. A catalytic NOx species acts as an electron transfer mediator to access a high-valent palladium intermediate as the presumed active oxidant.
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