Tetrahedron Letters p. 1599 - 1602 (2003)
Update date:2022-07-29
Topics:
Liao, Yuan-Xiu
Kuo, Pei-Yu
Yang, Ding-Yah
Various trisubstituted [1]benzopyrano[4,3-b]pyrrol-4(1H)-one derivatives have been synthesized from 4-hydroxycoumarin with a 30-40% yield over six steps. The key step of the synthesis is a base-promoted intramolecular cyclization of enamines 5, followed by dehydration to generate the fused pyrrole ring.
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