Magnetic nanofilms of nickel prepared at the liquid-liquid interface

Article abstract of DOI:10.1016/j.materresbull.2011.04.021

Thin films of metallic nickel with a thickness of the order of 20 nm have been prepared at the organic-aqueous interface at room temperature by the reaction of nickel cupferronate [Ni(C₆H₅N ₂O₂)₂] in toluene medium and sodium borohydride (NaBH₄) in aqueous medium. The films were characterized with transmission electron microscopy, scanning electron microscopy and atomic force microscopy. Thicker Ni films could be prepared by carrying out the reaction at the interface at 60 °C. The Ni nanofilms exhibit superparamagnetic behavior.