Journal of Fluorine Chemistry p. 357 - 362 (1988)
Update date:2022-08-05
Topics:
Jesudason, J. Joseph
Peach, Michael E.
The reactions of tin(II) benzenethiolate in DMF with hexafluorobenzene, chloropentafluorobenzene and bromopentafluorobenzene have been compared.Replacement of fluorine and chlorine by the phenylthio group and protodebromination were observed.DMF was a better solvent than either ethylene glycol/pyridine mixture (1:2) or diglyme for the reaction.New products have been isolated and characterized from the reactions of tin(II) p-chlorobenzenethiolate with hexafluorobenzene, decafluorobiphenyl, octafluorotoluene and pentafluorobenzyl bromide.
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