Tetrahedron p. 879 - 885 (1981)
Update date:2022-08-02
Topics:
Calmes, D.
Gorrichon-Guigon, L.
Maroni, P.
Accary, A.
Barret, R.
Huet, J.
The nucleophilic additions of hindered organometallic compounds to polycyclic ketones with trans ring junctions involve predominant axial attack when flattening of the ring containing the carbonyl group occurs.The influence of nucleophile structure (O-Por C-metalled character) on equatorial or axial attack is discussed.
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