Metal mediated one-pot synthesis of cyclopentanones from allyl vinyl esters or diallyl ethers via tandem Claisen rearrangement and hydroacylation

DOI: 10.1055/s-1995-3909

Source and publish data:

Synthesis p. 330 - 334 (1995)

Update date:2022-08-04

Topics:

Authors:

Eilbracht

Gersmeier

Lennartz

Huber Huber

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1995-3909

Cyclopentanones 3 and 7 are generated in a one-pot procedure from allyl vinyl ethers 1 and diallyl ethers 4, respectively. The conversion is carried out in the presence of RhCl(cod)(dppe) or RuCl₂(PPh₃)₃ at elevated temper

Full text of DOI:10.1055/s-1995-3909

Products guided by the article

Product name:Cyclopentanone, 2,3-dimethyl-3-(4-methylphenyl)-, trans-

Cas No:54750-41-3

R&D Labs maybe for 54750-41-3

GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
PINGYUAN SIHUAN PHARMACEUTICAL CO., LTD

Contact:+86-531-55696072

Address:#2766,yinxiu Road, Economic Development Zone, Pingyuan Country, Shandong Province, China.
Suzhou Lixin Pharmaceutical Co., Ltd.

Contact:86-512-88169812

Address:21 Tangxi Road, Suzhou New District, Suzhou 215151
Luojiang Chenming Biological Products Co

Contact:+86 15000297032

Address:GROUP NO.4, HE SHENG VILLAGE, PANLONG TOWN,
Shanghai Taibao Pharmaceutical Technology Co., Ltd(expird)

Contact:021-52217366

Address:shanghai

Relevant to this article

UV-VIS and ESR Spectroscopic Evidence for a Strongly ?-? Interacting (Resonant) Allodial Mixed-valence Compound: the Perchloro-4,4'-ethynylenebis(triphenylmethyl) Anion Radical

Doi:10.1039/c39940002521
(1994)
Highly chemoselective and efficient Strecker reaction of aldehydes with TMSCN catalyzed by MgI2 etherate under solvent-free conditions

Doi:10.1080/10426507.2019.1577846
(2019)
Rhodium-Catalyzed Addition of Alkyltrifluoroborate Salts to Imines

Doi:10.1002/adsc.201500295
(2015)
Directed ortho metalation approach to C-7-substituted indoles. Suzuki-Miyaura cross coupling and the synthesis of pyrrolophenanthridone alkaloids

Doi:10.1021/ol0344772
(2003)
Ag-catalyzed sulfonylation-peroxidation of alkenes with sulfonyl hydrazides and T-hydro

Doi:10.1016/j.tetlet.2018.09.045
(2018)
Synthesis of 5 membered heterocycles and related compounds

Doi:10.1248/cpb.22.2778
(1974)

Article Doi