Metal mediated one-pot synthesis of cyclopentanones from allyl vinyl esters or diallyl ethers via tandem Claisen rearrangement and hydroacylation

DOI: 10.1055/s-1995-3909

Source and publish data:

Synthesis p. 330 - 334 (1995)

Update date:2022-08-04

Topics:

Authors:

Eilbracht

Gersmeier

Lennartz

Huber Huber

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1995-3909

Cyclopentanones 3 and 7 are generated in a one-pot procedure from allyl vinyl ethers 1 and diallyl ethers 4, respectively. The conversion is carried out in the presence of RhCl(cod)(dppe) or RuCl₂(PPh₃)₃ at elevated temper

Full text of DOI:10.1055/s-1995-3909

Products guided by the article

Product name:Cyclopentanone, 2,3-dimethyl-3-(4-methylphenyl)-, trans-

Cas No:54750-41-3

R&D Labs maybe for 54750-41-3

Tianjin Crest Pharmaceutical R&D Co., Ltd. （Tianjin Yao Technology Development Co., Ltd.）(expird)

Contact:+86-22-66211386

Address:Building B5-405, No, 80 4th Avenue, TEDA, Tianjin, China P.R. 300457
Ji'nan Orgachem Pharmaceutical Co.,Ltd

Contact:+86-531-82687810

Address:Jinan
Suzhou Jingye Medicine & Chemical Co., Ltd

Contact:+86-512-66658588

Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Weinan Rigel Pharm Co., Ltd.

Contact:+86-913-2223392

Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China

Relevant to this article

UV-VIS and ESR Spectroscopic Evidence for a Strongly ?-? Interacting (Resonant) Allodial Mixed-valence Compound: the Perchloro-4,4'-ethynylenebis(triphenylmethyl) Anion Radical

Doi:10.1039/c39940002521
(1994)
Highly chemoselective and efficient Strecker reaction of aldehydes with TMSCN catalyzed by MgI2 etherate under solvent-free conditions

Doi:10.1080/10426507.2019.1577846
(2019)
Rhodium-Catalyzed Addition of Alkyltrifluoroborate Salts to Imines

Doi:10.1002/adsc.201500295
(2015)
Directed ortho metalation approach to C-7-substituted indoles. Suzuki-Miyaura cross coupling and the synthesis of pyrrolophenanthridone alkaloids

Doi:10.1021/ol0344772
(2003)
Ag-catalyzed sulfonylation-peroxidation of alkenes with sulfonyl hydrazides and T-hydro

Doi:10.1016/j.tetlet.2018.09.045
(2018)
Synthesis of 5 membered heterocycles and related compounds

Doi:10.1248/cpb.22.2778
(1974)

Article Doi