Metal mediated one-pot synthesis of cyclopentanones from allyl vinyl esters or diallyl ethers via tandem Claisen rearrangement and hydroacylation

DOI: 10.1055/s-1995-3909

Source and publish data:

Synthesis p. 330 - 334 (1995)

Update date:2022-08-04

Topics:

Authors:

Eilbracht

Gersmeier

Lennartz

Huber Huber

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Article abstract of DOI:10.1055/s-1995-3909

Cyclopentanones 3 and 7 are generated in a one-pot procedure from allyl vinyl ethers 1 and diallyl ethers 4, respectively. The conversion is carried out in the presence of RhCl(cod)(dppe) or RuCl₂(PPh₃)₃ at elevated temper

Full text of DOI:10.1055/s-1995-3909

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