Canadian Journal of Chemistry p. 1238 - 1243 (1982)
Update date:2022-08-05
Topics:
Abrams, S. R.
A number of isomeric tetradecynoic acids were isomerized with the sodium salt of 1,2-diaminoethane.Isomers having the triple bond near the carboxyl group rearranged to E,Z-3,5- and E,E-3,5-tetradecadienoic acids (1 and 2), the former compound being the sex pheromone of the black carpet beetle.Isomers having the triple bond closer to the terminus of the chain afforded some 13-tetradecynoic acid along with 1 and 2.Delocalized anions 12 and 13 are thought to contribute to the formation of 1 and 2.
View MoreZhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd
Contact:+86 411 84674606
Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
Tianjin Chemsyntech Chemical Co., Ltd
Contact:+86-22-60872258
Address:Haitai green industry base in Tianjin, K1,5-601
Zhejiang Sucon Silicone Co.,Ltd
Contact:+86-575-88046692
Address:Qisheng Rd., Paojiang Industrial Zone, Shaoxing, Zhejiang, China.
Nanjing lanbai chemical Co.,Ltd.
Contact:+86-25-85499326
Address:Room 908, 9F Taiyue Building,No.285 Heyan Road
Jining tiansheng chemical co.,ltd.
Contact:+86-537-5158722
Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Doi:10.1021/jo00902a007
(1975)Doi:10.1039/d0dt02829k
(2020)Doi:10.1016/0040-4020(96)00673-4
(1996)Doi:10.1016/S0040-4020(01)82438-8
(1984)Doi:10.3987/COM-14-13071
(2014)Doi:10.1016/j.tetlet.2016.04.015
(2016)
