Journal of the American Chemical Society p. 7241 - 7243 (1983)
Update date:2022-08-04
Topics:
Kunkely, Horst
Merz, Andreas
Vogler, Arnd
The complex ligand trans-4-styrylpyridine (trans-SP) is converted into its cis isomer (cis-SP) in the coordinated state upon simple alternating current electrolysis of the rhenium complex Re<(trans-SP)2(CO)3Cl> in acetonitrile/Bu4NCLO4 in an undivided electrochemical cell.Evidence is prresented that this reaction proceeds via an electronically excited state of the complex generated by cation-anion annihilation process.By the same method a CO vs.CH3CN ligand exchange is achieved with chromium hexacarbonyl.
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