Low-temperature Neutron Diffraction Study Of Bis(tri-p-tolylphosphine)heptahydridorhenium(VII), 2>: A Polyhydride Complex with Short H...H Contact that models an Intermediate Stage in the Oxidative Addition of Dihydrogen at Transition Metal Centres

DOI: 10.1039/c39910000241

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 241 - 243 (1991)

Update date:2022-08-04

Topics:

Authors:

Brammer, Lee

Howard, Judith A. K.

Johnson, Owen

Koetzle, Thomas F.

Spencer, John L.

Stringer, Andrew M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39910000241

Low-temperature neutron diffraction shows that the title compound has an H...H separation <1.357(7) Angstroem> intermediate in length between the accepted ranges for 'classical' non-bonded dihydrides and more recently reported dihydrogen ligands, thus providing a model for the intermediate stages of oxidative addition of dihydrogen at transition metal centres.

Full text of DOI:10.1039/c39910000241

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:bis(tri-p-tolylphosphine)heptahydridorhenium(VII)

Cas No:56226-01-8

R&D Labs maybe for 56226-01-8

Shandong Yaroma Perfumery Co., Ltd.

Contact:+86- 531- 88024598

Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
SHENZHEN PENGCHENG REDSTAR INDUSTRY CO.,LTD

Contact:+86-755-82412922

Address:Room 8066, East Block, Square City, Jiabin Road, Luohu District
KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Jiaxing Taixin Pharmaceutical Chemical Co., Ltd

Contact:0573-82613601

Address:Chemical Park, Jiaxing, Zhejiang, China
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA

Relevant to this article

Reconciling solvent effects on rotamer populations in carbohydrates - A joint MD and NMR analysis

Doi:10.1139/V06-036
(2006)
Doi:10.1039/P29750000665
(1975)
Role of O^- Ions in Charge-Transfer Reactions at the Surface of Silica-Supported Molybdenum Catalysts Prepared by the Grafting Method

Doi:10.1021/j100267a023
(1985)
A Multicomponent Electrosynthesis of 1,5-Disubstituted and 1-Aryl 1,2,4-Triazoles

Doi:10.1021/acs.joc.8b01808
(2018)
Doi:10.1016/0040-4020(75)80172-4
(1975)
The synthesis of carnosol derivatives

Doi:10.1016/S0040-4020(03)00412-5
(2003)

Article Doi