Low-temperature Neutron Diffraction Study Of Bis(tri-p-tolylphosphine)heptahydridorhenium(VII), 2>: A Polyhydride Complex with Short H...H Contact that models an Intermediate Stage in the Oxidative Addition of Dihydrogen at Transition Metal Centres

DOI: 10.1039/c39910000241

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 241 - 243 (1991)

Update date:2022-08-04

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Authors:

Brammer, Lee

Howard, Judith A. K.

Johnson, Owen

Koetzle, Thomas F.

Spencer, John L.

Stringer, Andrew M.

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Article abstract of DOI:10.1039/c39910000241

Low-temperature neutron diffraction shows that the title compound has an H...H separation <1.357(7) Angstroem> intermediate in length between the accepted ranges for 'classical' non-bonded dihydrides and more recently reported dihydrogen ligands, thus providing a model for the intermediate stages of oxidative addition of dihydrogen at transition metal centres.

Full text of DOI:10.1039/c39910000241

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