Journal of Organometallic Chemistry p. 301 - 312 (1983)
Update date:2022-08-03
Topics:
Zykov, B.G.
Erchak, N.P.
Khvostenko, V.I.
Lukevits, E.
Matorykina, V.F.
Asfandiarov, N.L.
The first vertical ?-ionization energies of substituted furans as determined by photoelectron spectroscopy are compared with the results of CNDO/2 calculations.The analysis of the photoelectron spectra and quantum chemical calculations for furylsilanes, difurylsilanes and some carbon analogs has shown the importance of the p?-d? interaction as well as of the conjugation and necessity of the inclusion of silicon d-atomic orbitals into the basic set.
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