Total Synthesis of dl-Cyclosativene by Cationic Olefinic and Acetylenic Cyclizations

DOI: 10.1021/jo01296a022

Source and publish data:

Journal of Organic Chemistry p. 1455 - 1462 (1980)

Update date:2022-08-03

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Authors:

Baldwin, Steven W.

Tomesch, John C.

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Article abstract of DOI:10.1021/jo01296a022

Racemic cyclosativene has been prepared stereospecifically by two routes each involving intramolecular capture of a homoallylic carbonium ion by a carbon-carbon multiple bond.Diels-Alder reaction between propynal and 2,3-dimethylcyclopentadiene followed b

Full text of DOI:10.1021/jo01296a022

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