Chemistry Letters p. 961 - 964 (1982)
Update date:2022-08-05
Topics:
Naruta, Yoshinori
Uno, Hidemitsu
Maruyama, Kazuhiro
Methyl 2-triorganosilyl-3-butenoates, which are selectively obtained from the carboxylation of the corresponding allylsilanes via allylic aluminates, react with various kinds of electrophiles to give γ substituted (E)-α,β-unsaturated esters in highly regio- and stereoselective manner with the aid of a Lewis acid.
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