Heterocycles p. 865 - 870 (1998)
Update date:2022-09-26
Topics:
Endo, Katsuya
Hirayama, Kaoru
Aota, Yuko
Seya, Kazuhiko
Asakura, Hirotatsu
Hisamichi, Kanehiko
Proline was decarboxylated quantitatively to Δ1-pyrroline on photoirradiation in the presence of rose bengal, while its methyl ester yielded an equimolar mixture of Δ1- and Δ5-pyrroline-2-carboxylic acid methyl esters. The decarboxylation of proline took place under either an aerobic (O2 bubbling) or an anaerobic (N2 bubbling) conditions, and under the latter condition, extent of the reaction depended on the amount of rose bengal employed. These results imply mechanistically that the reaction is the Type I photooxidation, indicating a new type of oxidative stress to natural secondary amines.
View Morewebsite:http://www.apeptides.com/en/
Contact:+86-21-60871011
Address:No. 80 Chuanshan Shuyuan Steet,Pudong,Shanghai
Contact:+86 18616952870
Address:Area
Tianjin Tongde Biological Technology Co., Ltd.
Contact:86-22-23309138
Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
TIANJIN FESTO CHEMICAL CO.,LTD(expird)
Contact:86-22-25814570
Address:No.12th,5th Ave.,TEDA,Tianjin,China
Contact:+86-571-87010026
Address:202, Zhenhua Road,
Doi:10.1021/acs.orglett.8b02663
(2018)Doi:10.1016/S0040-4039(01)01964-5
(2001)Doi:10.1016/j.farmac.2003.11.013
(2004)Doi:10.1021/ol802829n
(2009)Doi:10.1016/j.tetasy.2011.08.020
(2011)Doi:10.1021/jo0107756
(2002)
