STANNOUS TRIFLATE MEDIATED ALDOL REACTION OF 3-ACYLTHIAZOLIDINE-2-THIONE: A CONVENIENT METHOD FOR THE STEREOSELECTIVE SYNTHESIS OF β-HYDROXY ALDEHYDE AND β-HYDROXY CARBOXYLIC ACID DERIVATIVES

DOI: 10.1246/cl.1982.1903

Source and publish data:

Chemistry Letters p. 1903 - 1906 (1982)

Update date:2022-08-04

Topics:

Authors:

Mukaiyama, Teruaki

Iwasawa, Nobuharu

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Article abstract of DOI:10.1246/cl.1982.1903

Divalent tin enolates, formed from stannous triflate and 3-acylthiazolidine-2-thiones, react with aldehydes with erythro-selectivities.The adducts are easily transformed into β-hydroxy aldehyde and β-hydroxy carboxylic acid derivatives.

Full text of DOI:10.1246/cl.1982.1903

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