
Synthesis p. 419 - 422 (1995)
Update date:2022-09-26
Topics:
Vetter
Berkessel
The 1:1 complexes formed in situ from nickel(II) acetate and the thiosemicarbazones of ortho-hydroxy aromatic aldehydes catalyze the hydrosilylation of imines. A variety of imines were reduced in good to excellent yields employing two equivalents of a silane such as triethylsilane and 5 mol% of the catalysts.
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(1979)