Journal of the Chemical Society. Chemical communications p. 1163 - 1164 (1983)
Update date:2022-08-05
Topics:
Howard, Christopher G.
Girolami, Gregory S.
Wilkinson, Geoffrey
Thornton-Pett, Mark
Hursthouse, Michael B.
The interaction of tris(acetylacetonato)manganese(III), Mn(acac)3, with methyl-lithium in the presence of 1,2-bis(dimethylphosphino)ethane (dmpe) in diethyl ether leads, in a disproportionation reaction, to MnMe2(dmpe)2 and to MnMe4(dmpe) whose X-ray structure has been determined; also synthesised from Mn(acac)3 are MnMe4(PMe3)2 and the green tetrahedral alkyl complexes MnR4, R = CH2SiMe3 and CH2CMe3 which have been identified spectroscopically.
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