Journal of Organometallic Chemistry p. 89 - 93 (2003)
Update date:2022-08-03
Topics:
Sushev, Vyacheslav V.
Kornev, Alexander N.
Fedotova, Yana V.
Kursky, Yurii A.
Mushtina, Tatiana G.
Abakumov, Gleb A.
Zakharov, Lev N.
Rheingold, Arnold L.
Disproportionation of nickel(I) bis(triphenylphosphino)bis (trimethylsilyl)amide, (Ph3P)2Ni-N (SiMe3)2, in the presence of bis(diphenylphosphino)amine, (Ph2P)2NH, yields Ni(II) and Ni(0) phosphinoamide complexes: [N(Ph2P)2]2Ni (1), (Ph3P)2Ni[(Ph2P)2NH] (2). Ether solution, containing 2 and Ph3P (1:2) reacts with dioxygen (one equivalent) to form triphenylphosphinoxide adduct (Ph3P)2Ni[(Ph2P)2 NH·OPPh3] (3) in high yield. The crystal structures of compounds 1 and 3 have been determined by X-ray diffraction method.
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