Regiospecific Alkylation of 3-Substituted-2-cyclohexen-1-ones. Synthesis and Conformational Analysis of 6-(Carbethoxymethyl)-3-substituted-2-cyclohexen-1-ones

DOI: 10.1021/jo00286a023

Source and publish data:

Journal of Organic Chemistry p. 5919 - 5922 (1989)

Update date:2022-08-05

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Authors:

Podraza, Kenneth F.

Bassfield, Ronald L.

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Article abstract of DOI:10.1021/jo00286a023

The reaction of 3-substituted-2-cyclohexen-1-ones 1-5 with lithium diisopropylamide in tetrahydrofuran, followed by ethyl bromoacetate, generated 6-(carbethoxymethyl)-3-substituted-2-cyclohexen-1-ones 6-10 in a 55-88percent yield, regardless of the stoich

Full text of DOI:10.1021/jo00286a023

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