Regiospecific Alkylation of 3-Substituted-2-cyclohexen-1-ones. Synthesis and Conformational Analysis of 6-(Carbethoxymethyl)-3-substituted-2-cyclohexen-1-ones

DOI: 10.1021/jo00286a023

Source and publish data:

Journal of Organic Chemistry p. 5919 - 5922 (1989)

Update date:2022-08-05

Topics:

Authors:

Podraza, Kenneth F.

Bassfield, Ronald L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00286a023

The reaction of 3-substituted-2-cyclohexen-1-ones 1-5 with lithium diisopropylamide in tetrahydrofuran, followed by ethyl bromoacetate, generated 6-(carbethoxymethyl)-3-substituted-2-cyclohexen-1-ones 6-10 in a 55-88percent yield, regardless of the stoich

Full text of DOI:10.1021/jo00286a023

Products guided by the article

Product name:6-(carbethoxymethyl)-3-ethoxy-2-cyclohexen-1-one

Cas No:58775-57-8

R&D Labs maybe for 58775-57-8

Nantong Chem-land Co., Ltd.

Contact:86 513 85512619

Address:Rm.1306, Building A, Wenfeng Mansion,168 Gongnong Road, Nantong Jiangsu China
Taixing Joxin Bio-tec Co.,Ltd.

website:http://www.joxbio.com

Contact:86-523-87558858 87612088

Address:No.88, chengdong industrial park
Hubei Lingsheng Pharmaceuticals Co., Ltd.

Contact:+86-0710-3538058

Address:Xiangyang City Xiangcheng Economic Development Zone, Hubei Province
Xinji City Taida Sinopec Co., Ltd.

Contact:0086-311-85341278

Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China
Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China

Relevant to this article

Synthesis of 3-deazaguanine, 3-deazaguanosine, and 3-deazaguanylic acid by a novel ring closure of imidazole precursors.

Doi:10.1021/ja00422a036
(1976)
Doi:10.1021/ja01566a077
(1957)
Transition state stabilization by micelles: Thiolysis of p-nitrophenyl alkanoates in cetyltrimethylammonium bromide micelles

Doi:10.1139/v00-113
(2000)
Synthesis of 3-substituted quinolines via transition-metal-catalyzed reductive cyclization of o-nitro baylis-hillman acetates

Doi:10.1021/jo034447c
(2003)
Hydroalkylation of Unactivated Olefins via Visible-Light-Driven Dual Hydrogen Atom Transfer Catalysis

Doi:10.1021/jacs.1c05852
(2021)
Reactions of 4-aryl-2-hydrazino-3-nitro-6-R-quinolines with HNO₂

Doi:10.1023/A:1023966827299
(2003)

Article Doi