Journal of the American Chemical Society p. 2394 - 2398 (1983)
Update date:2022-08-05
Topics: IR spectroscopy Regioselectivity Electron transfer Lewis acid NMR spectroscopy Catalyst Mass spectrometry Nucleophile Electrophile Retro-aldol reaction Hydrogen bonding pH Michael addition Leaving group Tautomerism Buffer Solution Reaction Mechanism UV-Vis Spectroscopy Enolization Substitution Reaction Hydride Transfer Elimination Reaction Solvent Effects Substituent Effects Stereoselectivity Aldol Reaction Substrate Quenching Bond Cleavage Deuterium Labeling Activation Energy Thermodynamic Stability Acid-Base Catalysis Kinetic Control Thermodynamic Control Isotopic Labeling Activation Parameters Flash Photolysis Proton-Coupled Electron Transfer (PCET) Radical mechanism Potential Energy Surface (PES) Bronsted Acid Ionic Strength Kinetic Analysis Reaction rate Standard State Inhibition Lewis base Steric Effect Transition state
Koch, Heinz F.
Dahlberg, Donald B.
Lodder, Gerrit
Root, Karen S.
Touchette, Nancy A.
et al.
Rates and isotope effects are reported for benzylic hydron exchange and dehydrofluorination reactions of C6H5CiHClCF3 (I) and C6H5CiH(CF3)2 (II) in alcoholic sodium alkoxide solutions.Reactions of I were studied in ethanol and isotop
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