Tetrahedron Letters p. 5129 - 5132 (2003)
Update date:2022-08-03
Topics:
Smil, David V.
Laurent, Alain
Spassova, Nidejda S.
Fallis, Alex G.
A stereoselective Lewis acid-catalyzed and chelation controlled intramolecular Diels-Alder entry into the tricyclo[9.3.1.03,8]pentadecane core of aromatic C-ring taxanes is described. The approach affords an efficient, high yield, access to aromatic C-ring taxanes variably functionalized at the C2, C4, C5, and C9 positions.
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