Journal of the American Chemical Society p. 5709 - 5715 (1993)
Update date:2022-08-05
Topics:
Dua, Suresh K.
Whait, Robert B.
Alexander, Margaret J.
Hayes, Roger N.
Lebedev, Albert T.
Eichinger, Peter C. H.
Bowie, John H.
Deprotonated 1,2-diols and β-methoxyhydrins often eliminate ROH (R = H, Me) on collisional activation in the gas phase. These losses do not involve a negative ion pinacol rearrangement in acyclic systems in which there are no conformational restraints on
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