
Synthesis p. 454 - 456 (1991)
Update date:2022-08-04
Topics:
Tang
Wu
Zhang
A new convenient synthesis of S-alkyl O-aryl thiophosphoric acid derivatives is reported. The chlorination of O-aryl O,O-dialkyl thiophosphates with phosphorus oxychloride proceeds with isomerization to give S-alkyl O-aryl thiophosphorochloridates, which react further with various nucleophiles in the presence of base to give the title compounds.
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Doi:10.1070/MC2003v013n03ABEH001805
(1953)Doi:10.1021/om030331v
(2003)Doi:10.1248/cpb.35.3699
(1987)Doi:10.1016/S0957-4166(99)00074-9
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(2005)