A New ABCDE> Cycloaddition Strategy for the Approach to Yohimbe Alkaloids: Stereoselective Synthesis of (+/-)-3-epi-allo-Yohimbone

DOI: 10.1016/S0040-4039(00)61005-5

Source and publish data:

Tetrahedron Letters p. 6637 - 6640 (1992)

Update date:2022-08-05

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Authors:

Gomez-Pardo, Domingo

d'Angelo, Jean

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Article abstract of DOI:10.1016/S0040-4039(00)61005-5

Diels-Alder cycloaddition between lactam-sulfone 9 and diene 10 led to adducts 11 + 12 (30:1, respectively).Compound 11 has been converted in 4 steps into (+/-)-3-epi-allo-yohimbone 16.Key words: Diels-Alder cycloaddition, Yohimbe alkaloids, (+/-)-3-epi-a

Full text of DOI:10.1016/S0040-4039(00)61005-5

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