Journal of Organometallic Chemistry p. 297 - 310 (1986)
Update date:2022-08-03
Topics:
Suggs, J. William
Lee, Ken. S.
The ligands 8-(trimethylstannyl)methylquinoline, n-Bu3Sn(CH2)3NMe2 and Ph3Sn(CH2)3NMe2 Ph3Sn(CH2)3NMe2 react with (C6H5CN)2PdCl2 to give five-membered palladium chelates, in which the nitrogen atom was able to direct palladium insertion into a specific carbon-tin bond.The X-ray crystal structure of the simple chelate <(Me2N(CH2)3)PdCl>2 is presented.
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