Journal of the Chemical Society. Chemical communications p. 158 - 160 (1982)
Update date:2022-08-05
Topics:
Broadhurst, Michael J.
Hassall, Cedric H.
Thomas, Gareth J.
The Diels-Alder adduct prepared from the optically active, fully functionalised bicyclic precursor (8) and o-benzoquinone dimethide has been converted in good yield inmto (+)-4-demethoxydaunomycinone (13), glycosidation of which with the daunosamine derivative (14) gives 4-demethoxydaunomycin.
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