Chemistry of Natural Compounds p. 78 - 82 (1990)
Update date:2022-08-05
Topics:
Melikyan, G. G.
Mkrtchyan, V. M.
Atanesyan, K. A.
Azaryan, G. Kh.
Badanyan, Sh. O.
A preparative method has been developed for obtaining methyl (+/-)-tetradeca-2E,4,5-trienoate - the racemate of the sex pheromone of the dried-bean beetle.Using methyl 4-chlorotetradec-5-ynoate as an example, a detailed study has been made of the dependence of the regiochemistry of reduction on the activity of a zinc-copper couple, the methods of its activation, and the acidity of the proton donor.
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