Electron transfer and bond breaking. examples of passage from a sequential to a concerted mechanism in the electrochemical reductive cleavage of arylmethyl halides

DOI: 10.1021/ja00043a039

Source and publish data:

Journal of the American Chemical Society p. 6892 - 6904 (1992)

Update date:2022-08-04

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Authors:

Andrieux, Claude P.

Gorande, Annie Le

Savéant, Jean-Michel

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Article abstract of DOI:10.1021/ja00043a039

A systematic investigation of the kinetics of the electrochemical reduction of a series of 11 arylmethyl halides in acetonitrile and N′N′-dimethylformamide reveals a striking change in the reductive cleavage mechanism as a function of the energy of the π*

Full text of DOI:10.1021/ja00043a039

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