Tetrahedron Letters p. 6587 - 6590 (1993)
Update date:2022-07-30
Topics:
Kusuda, Shinya
Kawamura, Kiyoshi
Ueno, Yoshio
Toru, Takeshi
Both enentiomers of optically pure propargylic alcohols are conveniently prepared by the reaction of α-vinyl anion of 2-(trimethylsilyl)vinyl p-tolyl sulfoxide with aldehydes and subsequent either desilylsulfination or thermal elimination of the sulfinyl group.
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