THE SIMPLE SYNTHESIS OF ETHYL 2,4-DIENOATES FROM ALDEHYDES AND ETHYL 2-PHENYLSULFINYLACETATE

DOI: 10.1246/cl.1980.781

Source and publish data:

Chemistry Letters p. 781 - 782 (1980)

Update date:2022-07-30

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Authors:

Tanikaga, Rikuhei

Nishida, Masaharu

Ono, Noboru

Kaji, Aritsune

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Article abstract of DOI:10.1246/cl.1980.781

Treatment of aldehydes and ethyl 2-phenylsulfinylacetate (1) in the presence of piperidine gives Z-isomers (Z-2) of phenylsulfinyl-2-alkylideneacetates (2).Thermolysis of Z-2 results in the formation of ethyl E,E-2,4-dienoates (3).

Full text of DOI:10.1246/cl.1980.781

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