Synthesis of the C(19)-C(32) fragment of Scytophycin C via stereospecific methylation of γ,δ-epoxy acrylates with trimethylaluminum

DOI: 10.1016/S0040-4039(97)10782-1

Source and publish data:

Tetrahedron Letters p. 1125 - 1128 (1998)

Update date:2022-07-29

Topics:

Authors:

Grieco, Paul A.

Speake, Jason D.

Yeo, Sin Koo

Miyashita, Masaaki

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Article abstract of DOI:10.1016/S0040-4039(97)10782-1

The synthesis of the C(19) - C(32) fragment of Scytophycin C is described which features an iterative, stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum and the use of Roush's (S,S)-diisopropyltartrate-E-crotylboronate.

Full text of DOI:10.1016/S0040-4039(97)10782-1

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