Reduction-Oxidation Properties of Organotransition-metal Complexes. Part 12. Formation of Carbon-Carbon Bonds via the Oxidative Dimerisation of 4-C8H8)> and the Reduction of 5:η'5-C16H16)>2+

DOI: 10.1039/DT9810001317

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1317 - 1326 (1981)

Update date:2022-08-05

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Authors:

Connelly, Neil G.

Kelly, Raymond L.

Kitchen, Maureen D.

Mills, Rona M.

Stansfield, Robert F. D.

et al et al

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Article abstract of DOI:10.1039/DT9810001317

The complexes 4-cot)> <1: cot=cyclo-octatetraene; n=0-3, L=P(NM2)3, PPh3, P(OCH2)3CMe, or P(OPh)3> undergo chemically irreversible one-electron oxidation in Ch2Cl2 at a platinum electrode.Chemical generation of the highly reacti

Full text of DOI:10.1039/DT9810001317

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