Journal of the Chemical Society. Perkin transactions I p. 2245 - 2249 (1981)
Update date:2022-08-05
Topics:
Bruche, Luca
Garanti, Luisa
Zecchi, Gaetano
N-Aryl nitrile imines bearing a thioether function in the ortho-position were generated in situ on treating the corresponding hydrazonyl chlorides with triethylamine in boiling benzene.In all cases, the major products were 4,1,2-benzothiadiazines arising from intramolecular participarion of the sulphur and subsequent evolution of transient cyclic ylides.Minor products due to an intramolecular 1,3-dipolar cycloaddition were sometimes obtained.
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