Ready Nucleophilic Ring Opening of β-Epoxy-sulphone, -sulphoxide, and -ester with Grignard Reagents

DOI: 10.1039/c39860000836

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Journal of the Chemical Society. Chemical communications p. 836 - 837 (1986)

Update date:2022-08-03

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Authors:

Tanikaga, Rikuhei

Hosoya, Ken

Kaji, Aritsune

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Article abstract of DOI:10.1039/c39860000836

Treatment of β-epoxy-sulphone, -sulphoxide, and -ester with Grignard reagents and copper(I) iodide in diethyl ether-tetrahydrofuran at low temperature leads to rapid ring opening without loss of chirality.

Full text of DOI:10.1039/c39860000836

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