Tetrahedron p. 3961 - 3972 (1996)
Update date:2022-07-29
Topics:
Bowman, W. Russell
Forshaw, J. Anthony
Hall, Kevin P.
Kitchin, Jonathan P.
Mott, Andrew W.
The photographic process of 'infectious development' in which 1-acyl-2-arylhydrazines reduce Ag(I) has been studied using analogues. 1-Acyl-2-aryldiazenes, resulting from oxidation of 1-acyl-2-arylhydrazines, are hydrolysed to anions of aryldiazenes (ArN = NH), which undergo further oxidation with loss of nitrogen to yield aryl radicals. The aryl radicals cause 'feedback inhibition' which is prevented by the addition of benzhydrol.
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(1968)
