LA REACTION SN-Ge. ETUDE STEREOCHIMIQUE A PARTIR DES DIMETHYL-1,2 GERMACYCLOPENTANES

DOI: 10.1016/S0022-328X(00)88971-8

Source and publish data:

Journal of Organometallic Chemistry p. 25 - 36 (1981)

Update date:2022-07-30

Topics:

Authors:

Dubac, Jacques

Cavezzan, Jacques

Laporterie, Andre

Mazerolles, Pierre

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(00)88971-8

The stereochemistry of the nucleophilic substitution of various functional 1,2-dimethylgermacyclopentanes MeC4H7Ge(Me)X (X = Cl, OR, SR, NR2, PR2) by reducing reagents (LiAlH4, LiBH4), Grignard and organolithium compounds is studied.It depends both on the nucleophile and the leaving group.The results agree completely with those obtained in silicon series using optical NpPhRSi^*X or geometrical MeC4H7Si(Me)X isomers.

Full text of DOI:10.1016/S0022-328X(00)88971-8

Products guided by the article

Product name:Germolane, 1,2-dimethyl-1-phenyl-, cis-

Cas No:63453-20-3

R&D Labs maybe for 63453-20-3

Advanced Biotech

Contact:+1-973-357-0577

Address:10 Taft Rd.
ALPHA PHARMACEUTICAL CO，LTD JIANGSU

Contact:+86-527-84829968,+86-527-84829998

Address:suqian city
EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China

Relevant to this article

Antitumour polycyclic acridines. Palladium(0) mediated syntheses of quino[4,3,2-kl]acridines bearing peripheral substituents as potential telomere maintenance inhibitors

Doi:10.1039/b305177n
(2003)
Doi:10.1557/JMR.2000.0081
(1923)
Reaction of 3-oxo-N-phenylbutanethioamide with 5-amino-1H-1,2,4-triazoles

Doi:10.1134/S1070428006100216
(2006)
Mass spectrometry in structural and stereochemical problems. CCXXX. Preparation of 5α,20α and 5α,17α,20α cholestane 3β,6α diol. Electron impact induced fragmentation of steroidal Δ17(20), Δ20(21), and Δ20(22) olefins

Doi:10.1021/jo00960a024
(1973)
Asymmetric total synthesis of (-)-VM55599: Establishment of the absolute stereochemistry and biogenetic implications

Doi:10.1021/ja017425l
(2002)
Doi:10.1021/jm00280a007
(1972)

Article Doi