Tetrahedron p. 3677 - 3694 (1984)
Update date:2022-09-26
Topics:
Krohn, Karsten
Klimars, Michael
Koehle, Hans-Juergen
Ebeling, Eckehardt
7,10-O-Dimethyl-ξ-pyrromycinone (78) and the not naturally occurring 7-deoxyanthracyclinones 76 and 77 are prepared via base induced cyclization of the ketoesters 73-75, and stereoselectively hydroxylated to the 2,4-cis diols 83 and 85.
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