Journal of Organometallic Chemistry p. C7 - C12 (1982)
Update date:2022-08-03
Topics:
Vol'kenau, N. A.
Petrakova, V. A.
Electroneutral benzenecyclopentadienyliron reacts with oxygen under strictly aprotic conditions to give a crystalline peroxidic dimer.The cyclohexadienyl-cyclopentadienyl structure of the latter, with a peroxide bridge between the six-membered ligands of the two moieties of the molecule, is determined by 1H NMR spectroscopy.Reactions of this new peroxidic dimer with several reagents, i.e.HCl, H2O, C2H5OH, C6H5SH, C6H5COCl, CHCl3, CH3COCH3, are described.
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