Journal of the Chemical Society. Perkin transactions I p. 621 - 632 (1981)
Update date:2022-08-03
Topics:
Bloodworth, A.J.
Khan, Jamil A.
Loveitt, M.E.
The bis-mercuriated derivative (12) of 9,10-dioxabicyclo<3.3.2>decane has been prepared by peroxymercuriation of cis,cis-octa-1,5-diene, but substantial amounts of bicyclic ethers are also formed in the reaction.The bicyclic peroxides (4) and (5) have been obtained from (12) by reduction and brominolysis respectively. 8,9-Dioxabicyclo<5.2.1>decane (6) and the dibromo-derivative (7) have similarly been prepared by peroxymercuriation and demercuriation of cyclo-octa-1,4-diene.It is suggested that the isomeric purity of the peroxides and the concurrent formation of bicyclic ethers both result from equilibrium control of reversible (per)oxymercuriation-de(per)oxymercuriation.A low yield of the <3.2.1>-peroxide (8) has been obtained by peroxymercuriation and brominolysis of cyclohexa-1,4-diene, but attempts to prepare <2.2.1>-compounds from 5,5-disubstituted cyclopentadienes have been unsuccessful.
View MoreBinzhou Holly Pharmaceutical Co.,Ltd.
Contact:74517
Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
Hangzhou Sartort Biopharma Co., Ltd
website:http://www.sartort.com
Contact:86-571-87039693
Address:No. 57, Tech Park Road, Hangzhou, Zhejiang, China
Chengdu Pukang Biotechnology Co., Ltd
Contact:+86-28-82550498
Address:No. 558 Rulin Road,Xinjin county,Chengdu city, China
Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd
Contact:+86 411 84674606
Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
SHANDONG AONA CHEMICAL CO.,LTD.
Contact:86-532-85762926
Address:LIUYUAN TOWN, ZAOZHUANG CITY, SHANGDONG PROVINCE.
Doi:10.1016/S0020-1693(03)00149-X
(2003)Doi:10.1007/BF01798084
(1938)Doi:10.1002/adsc.202001016
(2021)Doi:10.1016/S0040-4039(01)83260-3
(1977)Doi:10.1016/j.ica.2004.10.036
(2005)Doi:10.1021/op300147f
(2013)
