Journal of the Chemical Society. Perkin transactions I p. 621 - 632 (1981)
Update date:2022-08-03
Topics:
Bloodworth, A.J.
Khan, Jamil A.
Loveitt, M.E.
The bis-mercuriated derivative (12) of 9,10-dioxabicyclo<3.3.2>decane has been prepared by peroxymercuriation of cis,cis-octa-1,5-diene, but substantial amounts of bicyclic ethers are also formed in the reaction.The bicyclic peroxides (4) and (5) have been obtained from (12) by reduction and brominolysis respectively. 8,9-Dioxabicyclo<5.2.1>decane (6) and the dibromo-derivative (7) have similarly been prepared by peroxymercuriation and demercuriation of cyclo-octa-1,4-diene.It is suggested that the isomeric purity of the peroxides and the concurrent formation of bicyclic ethers both result from equilibrium control of reversible (per)oxymercuriation-de(per)oxymercuriation.A low yield of the <3.2.1>-peroxide (8) has been obtained by peroxymercuriation and brominolysis of cyclohexa-1,4-diene, but attempts to prepare <2.2.1>-compounds from 5,5-disubstituted cyclopentadienes have been unsuccessful.
View MoreNINGBO PANGS CHEM INT’L CO., LTD.
Contact:+86-0574-27666801
Address:Floor 21, Building 11, Xintiandi, No. 689, Shijiroad, Ningbo, Zhejiang, China
Contact:86-571-86737118-8689
Address:No.69, 12 Street, HEDA, Hangzhou, Zhejiang, China
Hangzhou Haiqiang Chemical Co.,Ltd.
Contact:+86-571-86960370
Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
Suzhou BEC Fine Chemicals Co., Ltd.
website:http://www.bek.com.cn
Contact:0512-68095917 18913193865
Address:6, Jin Shan Road, Suzhou New District, 215011 China Suzhou Nations Pharmaceutical Innovation Center Inside
Wuhan Chemchemical Co., Ltd.(expird)
Contact:15973022782
Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.
Doi:10.1016/S0020-1693(03)00149-X
(2003)Doi:10.1007/BF01798084
(1938)Doi:10.1002/adsc.202001016
(2021)Doi:10.1016/S0040-4039(01)83260-3
(1977)Doi:10.1016/j.ica.2004.10.036
(2005)Doi:10.1021/op300147f
(2013)
