Journal of the Chemical Society. Perkin transactions I p. 1324 - 1330 (1980)
Update date:2022-08-05
Topics:
Jessep, Michael A.
Leaver, Derek
The title compound is obtained (i) by the reaction of 5-(NN-dimethylaminomethylene)-1-(NN-dimethyliminiomethyl)cyclopenta-1,3-diene perchlorate with the conjugate base of 3H-pyrrolizine or (ii), in better yield, by the reaction of 3,5-bis-(NN-dimethylaminomethylene)-3H,5H-pyrrolizinium perchlorate with the conjugate base of cyclopentadiene.The compound resembles azulene in its visible and near-u.v. spectrum and in the ease of electrophilic attack in the five-membered carbocyclic ring (position 6 and 8).Products of acylation, nitration, nitrosation, bromination, and NN-dimethylaminomethylation are described.
View MoreArshine Pharmaceutical Co., Limited
website:http://www.cnarshine.com
Contact:0731-88503671
Address:Room 1109.Block C3, Lugu Enterprise Plaza,No.27 Wenxuan Road,Changsha National Hi-Tech Industrial Development Zone,Hunan ,P.R.China
Jiaozuo Zhongwen Trading Coporation Limited
Contact:--
Address:East Renmin Road
Twin International Co., Limited
Contact:+86-21-80309280
Address:No.345 Jinxiang Road, Jinqiao Export Processing Zone
website:http://www.ringchemicals.com/
Contact:+1-416-493-6870
Address:Toronto, Canada
Jiangsu Cale New Material Co.ltd
Contact:+86-515-88334667/88203550
Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Doi:10.1039/j39700001469
(1970)Doi:10.1016/S0957-4166(99)00554-6
(2000)Doi:10.1016/j.tet.2018.06.022
(2018)Doi:10.1016/S0960-894X(99)00081-5
(1999)Doi:10.1002/(SICI)1099-0690(200005)2000:9<1745::AID-EJOC1745>3.0.CO;2-8
(2000)Doi:10.1016/S0020-1693(99)00581-2
(2000)
