Journal of the Chemical Society. Perkin transactions I p. 1324 - 1330 (1980)
Update date:2022-08-05
Topics:
Jessep, Michael A.
Leaver, Derek
The title compound is obtained (i) by the reaction of 5-(NN-dimethylaminomethylene)-1-(NN-dimethyliminiomethyl)cyclopenta-1,3-diene perchlorate with the conjugate base of 3H-pyrrolizine or (ii), in better yield, by the reaction of 3,5-bis-(NN-dimethylaminomethylene)-3H,5H-pyrrolizinium perchlorate with the conjugate base of cyclopentadiene.The compound resembles azulene in its visible and near-u.v. spectrum and in the ease of electrophilic attack in the five-membered carbocyclic ring (position 6 and 8).Products of acylation, nitration, nitrosation, bromination, and NN-dimethylaminomethylation are described.
View MoreContact:86-21-57725962
Address:shanghai
Nanjing distinctions Medical Technology Co., Ltd.(expird)
Contact:+86-15996203785 13914714059
Address:nanjing,jiangsu , China
TIANJIN FESTO CHEMICAL CO.,LTD(expird)
Contact:86-22-25814570
Address:No.12th,5th Ave.,TEDA,Tianjin,China
Contact:86-575-86132822，86-575-86085355
Address:No.418 Dadao West Road,Qixing Street,Xinchang, Zhejiang Province, China.
LianYunGang Chiral Chemical(CHINA) CO.,LTD
Contact:+86-518-83616958 +86-519-82884848
Address:LianYunGang Chemical Industry Park (JiangSu)
Doi:10.1039/j39700001469
(1970)Doi:10.1016/S0957-4166(99)00554-6
(2000)Doi:10.1016/j.tet.2018.06.022
(2018)Doi:10.1016/S0960-894X(99)00081-5
(1999)Doi:10.1002/(SICI)1099-0690(200005)2000:9<1745::AID-EJOC1745>3.0.CO;2-8
(2000)Doi:10.1016/S0020-1693(99)00581-2
(2000)
