
Journal of the Chemical Society. Perkin transactions I p. 1312 - 1316 (1981)
Update date:2022-07-29
Topics:
Finch, Mark A. W.
Roberts, Stanley M.
Newton, Roger F.
The known hydroxy-aldehyde (5) has been converted into 6β-decarboxyprostaglandin I1 (19) and 6β-prostaglandin I1 (3) by (i) reaction with an appropriate organometallic reagent, (ii) cyclisation via the intermediate formation of an iodonium ion, and (iii) hydrodeiodination and desilylation.
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